Chemistry 351
The Second Law I
- Spontaneous Changes and Entropy (S)
- Free Energy Functions (A and G)
The Second Law II
- Maxwell Relations
- The Difference between Cp and CV
Mixtures and Solutions
- Thermodynamics of mixing
- Colligative Properties
Phase Changes
- The Calpeyron and Clasius-Clapeyron Equations
- Phase Diagrams for Single Component Systems
- Phase Diagrams for Two Component Systems
Equilibrium
- Thermodynamic Criterion for Equilibrium
- Equilibrium in the Gas Phase
- Acid/Base Equilibrium
Electrochemistry
- Electrolytic Changes
- Galvanic Changes
- Electrochemistry and Equilibrium
Chemical Kinetics I
- Rate Laws
- Order
- Empirical Methods
- The Method of Half-Lives
- The Method of Initial Rates
- The rate Constant
Chemical Kinetics II
- Reaction Mechanisms
- Elementary Steps
- The Rate-Determining Step Approximation
- The Steady-State Approximation
- The Equilibrium Approximation
- Selected Mechanisms and Their Applications