Balancing Chemical Reaction Equations

There are a number of methods which can be used to balance chemical reaction equations.The simplest is the "by inspection" method. To use this method, simply work from the most complex chemical formula to the simplest. Balance the major atoms first leaving hydrogen and oxygen until last. If polyatomic ions are involved and they do not change in the reaction, balance them as a whole group.

Here is an example. Consider the oxidation of propane.

__ C3H8 + __O2 --> __CO2 + __H2O

The most complexe coumpund is propane. The carbon atoms will balance if the coefficient on carbon dioxide is 3.

__ C3H8 + __O2 --> 3 CO2 + __H2O

Next, the hydrogens will balance if the coefficient on water is 4.

__ C3H8 + __O2 --> 3 CO2 + 4 H2O

No there are 10 oxygen atoms depicted on the products side of the reation so the coefficient on oxygen (on the reactants side) must be 5.

__ C3H8 + 5 O2 --> 3 CO2 + 4 H2O

These numbers were chosen assuming the coefficient on propane was 1.

1 C3H8 + 5 O2 --> 3 CO2 + 4 H2O

So the final balanced reaction equation is:

C3H8 + 5 O2 --> 3 CO2 + 4 H2O

The sum of the coefficients of the reactants and the products in this reaction is 13.

Note: A properly balanced reaction equation will always use the smallest whole numbers which are possible. Thus, while a reaction such as

C4H10 + 13/2 O2 --> 4 CO2 + 5 H2O

is technically balanced, it is only properly balanced as

2 C4H10 + 13 O2 --> 8 CO2 + 10 H2O

since this equation contains no fractions.

Here are some problems for you to try

Balance the following reaction equation. What is the sum of the coefficients of the reactants and products?

__COCl2 + __H2O --> __CO2 + __HCl

4 5 6 8 12
I need help with this problem.

Balance the following reaction equation. What is the sum of the coefficients of the reactants and products?

__Al4C3 + __HCl --> __AlCl3 + __CH4

20 24 16 18 12
I need help with this problem.

Balance the following reaction equation. What is the sum of the coefficients of the reactants and products?

__Fe2O3 + __CO --> __CO2 + __Fe

5 6 7 8 9
I need help with this problem.

Balance the following reaction equation. What is the sum of the coefficients of the reactants and products?

__C4H10O + __O2 --> __CO2 + __H2O

12 14 16 18 19
I need help with this problem.

Balance the following reaction equation. What is the sum of the coefficients of the reactants and products?

__Mg + __FeCl3 --> __MgCl2 + __FeCl2

3 5 6 10 12
I need help with this problem.

Balance the following reaction equation. What is the sum of the coefficients of the reactants and products?

__CuCl2 + __KI --> __CuI + __KCl + __I2

9 10 12 13 18
I need help with this problem.

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Patrick E. Fleming
Department of Chemistry and Biochemistry
California State University, East Bay
patrick.fleming@csueastbay.edu